Rainfall intensity affects runoff responses in a semi-arid catchment

The source and hydrochemical makeup of a stream reflects the connectivity between rainfall, groundwater, the stream, and is reflected to water quantity and quality of the catchment. However, in a semi-arid, thick, loess covered catchment, temporal variation of stream source and event associated behaviours are lesser known. Thus, the isotopic and chemical hydrographs in a widely distributed, deep loess, semi-arid catchment of the northern Chinese Loess Plateau were characterized to determine the source and hydrochemical behaviours of the stream during intra-rainfall events. Rainfall and streamflow were sampled during six hydrologic events coupled with measurements of stream baseflow and groundwater. The deuterium isotope (²H), major ions (Cl⁻, SO₄²⁻, NO₃⁻, Ca²⁺, K⁺, Mg²⁺, and Na⁺) were evaluated in water samples obtained during rainfall events. Temporal variation of ²H and Cl⁻ measured in the groundwater and stream baseflow prior to rainfall was similar; however, the isotope compositions of the streamflow fluctuated significantly and responded quickly to rainfall events, likely due to an infiltration excess, overland dominated surface runoff during torrential rainfall events. Time source separation using ²H demonstrated greater than 72% on average, the stream composition was event water during torrential rainfall events, with the proportion increasing with rainfall intensity. Solutes concentrations in the stream had loglinear relationships with stream discharge, with an outling anomaly with an example of an intra-rainfall event on Oct. 24, 2015. Stream Cl⁻ behaved nonconservative during rainfall events, temporal variation of Cl⁻ indicated a flush and washout at the onset of small rainfall events, a dilution but still high concentration pattern in high discharge and old water dominated in regression flow period. This study indicates rainfall intensity affects runoff responses in a semi-arid catchment, and the stored water in the thick, loess covered areas was less connected with stream runoff. Solute transport may threaten water quality in the area, requiring further analysis of the performance of the eco-restoration project.     

Seasonal connections between meteoric water and streamflow generation along a mountain headwater stream

In snowmelt-driven mountain watersheds, the hydrologic connectivity between meteoric waters and stream flow generation varies strongly with the season, reflecting variable connection to soil and groundwater storage within the watershed. This variable connectivity regulates how streamflow generation mechanisms transform the seasonal and elevational variation in oxygen and hydrogen isotopic composition (δ¹⁸O and δD) of meteoric precipitation. Thus, water isotopes in stream flow can signal immediate connectivity or more prolonged mixing, especially in high-relief mountainous catchments. We characterized δ¹⁸O and δD values in stream water along an elevational gradient in a mountain headwater catchment in southwestern Montana. Stream water isotopic compositions related most strongly to elevation between February and March, exhibiting higher δ¹⁸O and δD values with decreasing elevation. These elevational isotopic lapse rates likely reflect increased connection between stream flow and proximal snow-derived water sources heavily subject to elevational isotopic effects. These patterns disappeared during summer sampling, when consistently lower δ¹⁸O and δD values of stream water reflected contributions from snowmelt or colder rainfall, despite much higher δ¹⁸O and δD values expected in warmer seasonal rainfall. The consistently low isotopic values and absence of a trend with elevation during summer suggest lower connectivity between summer precipitation and stream flow generation as a consequence of drier soils and greater transpiration. As further evidence of intermittent seasonal connectivity between the stream and adjacent groundwaters, we observed a late-winter flush of nitrate into the stream at higher elevations, consistent with increased connection to accumulating mineralized nitrogen in riparian wetlands. This pattern was distinct from mid-summer patterns of nitrate loading at lower elevations that suggested heightened human recreational activity along the stream corridor. These observations provide insights linking stream flow generation and seasonal water storage in high elevation mountainous watersheds. Greater understanding of the connections between surface water, soil water and groundwater in these environments will help predict how the quality and quantity of mountain runoff will respond to changing climate and allow better informed water management decisions.     

Petrochronology of oxidized granulites from southern Peru

Sapphirine–quartz granulites from the Cocachacra region of the Arequipa Massif in southern Peru record early Neoproterozoic ultrahigh‐temperature metamorphism. Phase equilibrium modelling and zircon petrochronology are used to quantify timing and pressure–temperature (P–T) conditions of metamorphism. Modelling of three magnetite‐bearing sapphirine–quartz samples indicates peak temperatures of >950°C at ~0.7 GPa and a clockwise P–T evolution. Elevated concentrations of Al in orthopyroxene are also consistent with ultrahigh‐temperature conditions. Neoblastic zircon records ages of c. 1.0–0.9 Ga that are interpreted to record protracted ultrahigh‐temperature metamorphism. Th/U ratios of zircon of up to 100 reflect U‐depleted whole‐rock compositions. Concentrations of heavy rare earth elements in zircon do not show systematic trends with U–Pb age but do correlate with variable whole‐rock compositions. Very large positive Ce anomalies in zircon from two samples probably relate to strongly oxidizing conditions during neoblastic zircon crystallization. Low concentrations of Ti‐in‐zircon (<10 ppm) are interpreted to result from reduced titania activities due to the strongly oxidized nature of the granulites and the sequestration of titanium‐rich minerals away from the reaction volume. Whole‐rock compositions and oxidation state have a strong influence on the trace element composition of metamorphic zircon, which has implications for interpreting the geological significance of ages retrieved from zircon in oxidized metamorphic rocks.     

Smectite formation in metalliferous sediments near the East Pacific Rise at 13°N

A 43 cm long E271 sediment core collected near the East Pacific Rise(EPR) at 13°N were studied to investigate the origin of smectite for understanding better the geochemical behavior of hydrothermal material after deposition.E271 sediments are typical metalliferous sediments. After removal of organic matter, carbonate, biogenic opal,and Fe-Mn oxide by a series of chemical procedures, clay minerals(2 μm) were investigated by X-ray diffraction,chemical analysis and Si isotope analysis. Due to the influence of seafloor hydrothermal activity and close to continent, the sources of clay minerals are complex. Illite, chlorite and kaolinite are suggested to be transported from either North or Central America by rivers or winds, but smectite is authigenic. It is enriched in iron, and its contents are highest in clay minerals. Data show that smectite is most likely formed by the reaction of hydrothermal Fe-oxyhydroxide with silica and seawater in metalliferous sediments. The Si that participates in this reaction may be derived from siliceous microfossils(diatoms or radiolarians), hydrothermal fluids, or detrital mineral phases. And their δ30 Si values are higher than those of authigenic smectites, which implies that a Si isotope fractionation occurs during the formation because of the selective absorption of light Si isotopes onto Feoxyhydroxides. Sm/Fe mass ratios(a proxy for overall REE/Fe ratio) in E271 clay minerals are lower than those in metalliferous sediments, as well as distal hydrothermal plume particles and terrigenous clay minerals. This result suggests that some REE are lost during the smectite formation, perhaps because their large ionic radii of REE scavenged by Fe-oxyhydroxides preclude substitution in either tetrahedral or octahedral lattice sites of this mineral structure, which decreases the value of metalliferous sediments as a potential resource for REE.     

Otolith microchemistry indicates regional phylopatry in the larval phase of an amphidromous fish (Gobiomorphus hubbsi)

Knowledge of stock structure is key for the effective management of any fish species. Amphidromous fish, which live and spawn in freshwater but spend a pelagic larval period at sea, have typically been assumed to disperse widely during their larval phase, resulting in populations being sourced from a single unstructured larval pool. We used otolith microchemical analysis to examine the stock structure of bluegill bully (Gobiomorphus hubbsi), a declining amphidromous eleotrid endemic to New Zealand, along the west coast of South Island, New Zealand. Some drainages – even those in close proximity (c. 20?km) – were readily distinguishable based on otolith trace element concentrations, while little structure was evident between other geographically disparate locations. These results indicate that, at least in some cases, locally retained larvae, rather than a single unstructured larval pool, dominates recruitment. Management of bluegill bully and other amphidromous species must therefore consider the possibility of regionally distinct populations.     

A multi‐method approach to dating the burial and skeleton of Kiacatoo Man,New South Wales,Australia

Kiacatoo Man, a large, rugged Aboriginal adult buried in the Lachlan riverine plains of southeastern Australia, was discovered in 2011. Laser‐ablation uranium series analysis on bone yielded a minimum age for the burial of 27.4 ± 0.4 ka (2σ). Single‐grain, optically stimulated luminescence ages on quartz sediment in which the grave had been dug gave a weighted mean age of 26.4 ± 1.5 ka (1σ). Luminescence samples from the grave infill and from sediment beneath the grave exhibit overdispersed dose distributions consistent with bioturbation or other disturbance, which has obscured the burial signal. The overlap between the minimum (U‐series) and maximum (luminescence) ages places the burial between 27.0 and 29.4 ka (2σ). Luminescence ages obtained from the channel belt of between 28 ± 2 and 25 ± 3 ka indicate that fluvial sedimentation was occurring before the Last Glacial Maximum, which is consistent with the broader geomorphic setting. Together, these results are internally and regionally consistent, and indicate that Kiacatoo Man was one of the more ancient individuals so far identified in Australia. His remains are important to our understanding of patterns of biological variation and other processes that have shaped people in the Murray‐Darling Basin through time. Copyright © 2019 John Wiley & Sons, Ltd.     

黑河中游夏季昼夜水汽同位素特征及水汽来源分析

基于2012年6~8月的实测水汽同位素数据及相关气象数据，对黑河中游夏季昼夜的同位素基本特征、水汽来源方向及潜在蒸发源地进行了研究。结果表明：空气水汽线斜率白天大于夜晚和水汽过量氘值白天大于夜晚，综合说明白天局地蒸发较夜晚强烈；夏季受西风水汽影响显著。其中，6月主要受西风水汽和北冰洋水汽影响，7、8月主要受西风水汽和东南方向水汽影响，且8月受东南方向水汽影响最为明显；水汽运移路径上下垫面地形和气压带移动会影响水汽后向轨迹高度，西北方向上水汽输送通道较顺畅，风速较大，有利于水汽的输送；水汽蒸发源地主要集中在研究区周围及以东、以北部，其次是西北部。绿洲是主要的水汽蒸发源地，其次是城市和河流，白天较夜晚局地蒸发强烈且面积大。     

基于细分行业的安徽省创新型企业集聚研究

创新型企业作为塑造创新地理格局的重要力量，其区位选择的外部特征及内在机理亟须予以系统化研究。基于对安徽省创新型企业的细分行业与空间建库，采用核密度估计和地理探测器等方法，对细分行业下的创新型企业空间集聚特征及影响因素进行研究。结果表明：（1）安徽省创新型企业类型以先进制造和自动化为主，并以生物与新医药、新材料、电子信息为辅；（2）创新型企业空间集聚的不均衡特征显著，呈现出“一核一带多节点”的集聚分布特征，且合肥、芜湖是两个重要集聚区；不同细分行业视角下创新型企业的空间分布形态各异，可归纳为点-轴式、极核式、双核式及多核分散式等4种空间组织形态。（3）创新型因子对于创新型企业的空间集聚最为重要，但传统型和政策型因子的重要性仍不容忽视。其中，产业基础、人力资本、创新投入是最核心的因素，但各行业创新型企业的影响因素作用力则表现出一定的异质性。     

粤东海涂土壤及其利用

粤东海岸东起闽粤交界的大埕湾,西迄深圳市的大鹏湾,岸线曲折,港湾较多,河溪人海泥沙在潮间带及紧邻5m 等深线以内形成大片海涂,土壤类型多样,以泥质和沙泥质土壤为主;除河口湾的土壤含盐量低外,其余较高;土壤有机质含量中等,钾素较丰富,磷素较低。因地处亚热带南缘,光、热和水资源条件较好,且多数海湾有深入内地的小海湾和潮沟,甚适合发展海水养殖与晒盐,韩江口的义丰河和海门龟头海大闸外等滩地尚有围垦价值。多处海湾潮滩沙土适合作海滨浴场,也有小片滩地红树林适合旅游观赏。     

青海可可西里地区综合科学考察初报

本区至今还是综合科学考察的空白区。为查明基本情况,1989年夏以乘汽车路线考察方式穿行该区而作了预查,搜集了当地地质、地理、生物等基本资料。经考察发现,区内野生动物资源丰富,上新世以来火山活动普遍,湖泊众多,矿产资源可能有良好前景;所在区又为自然地域和地质构造的重要界线,对青藏高原研究具有重大科学价值。